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Why Do Minerals Fluoresce?

Why Do Minerals Fluoresce?

Let's explore the wonderful world of Fluorescent Minerals! These magical minerals (and fossils) appear to glow when exposed to ultraviolet (UV) light. Here you'll learn about different wavelengths of light, why some rocks fluoresce and others don't, and how to get fluorescent minerals and fossils to glow!

Viewing Minerals in Regular Light vs. UV Light

When you observe a crystal or mineral specimen under regular visible light, the specimen is naturally absorbing certain wavelengths, and reflecting others. The color we observe in a mineral specimen is the wavelength which is NOT absorbed by the mineral, but the one that is reflected back to our eye. 

If, however, you were to turn all the lights off in your room, or shut your curtains and use a blacklight or ultraviolet (UV) light on certain minerals, they may appear to glow!

An assortment of minerals and fossils displaying UV fluorescence

An assortment of minerals and fossils displaying UV fluorescence

UV light is similar to regular visible light, but it has a much higher energy and shorter wavelength than visible light. 

We can't see UV light, but when you observe a fluorescent mineral being exposed to UV light, it appears to glow. It is emitting light back to our eye that IS within our visible range of light.

So what is happening here?

What is Fluorescence?

When you shine a UV light on a mineral, electrons within the atomic structure of the mineral are undergoing energy transitions, in which they are absorbing energy from the UV light source and re-emitting it as visible light. 

Fluorescence in minerals occurs when ultraviolet light (invisible to our naked eye), causes electron displacement within a minerals atomic structure. This allows the mineral to temporarily absorb the ultraviolet light and emit it as visible light which we can see. 

 

Fluorescence is the temporary absorption of electromagnetic wavelengths by fluorescent molecules, which then emit that light at a lower energy level or wavelength which we can see. 

If you observe a mineral displaying UV fluorescence, you are viewing the emission of light by a mineral that has temporarily absorbed the UV light. So the fluorescent molecules present in some minerals temporarily absorbs the ultraviolet light, and emits it back at a lower level that we can easily observe.

Remember, visible light has a longer wavelength or lower energy than ultraviolet light, which has a shorter, higher energy wavelength. That means we can't readily see ultraviolet light within our visible spectrum of light. 


How do we Observe Fluorescence?

When we view light, we are seeing light reflected off of objects. The objects appear certain colors to our eyes based upon the wavelengths of light absorbed by that object. For example, if we observe a green Fluorite crystal, we are seeing the wavelengths that are NOT absorbed by the Fluorite, so the wavelength ultimately reflected back to our eyes is green.

With UV light, the UV radiation is actually absorbed and then re-emitted by the object. Some minerals, like Fluorite, fluoresce easily under UV light. In fact the word fluorescence actually comes from the mineral Fluorite, since Fluorite was the first documented observation of a mineral fluorescing!

Fluorite under regular light (left) and UV fluorescing (right)
Fluorite crystals under regular light (left) and Ultraviolet light (right)

 

But not all minerals, and not even all Fluorite specimens fluoresce....what gives? 

How Do Minerals Fluoresce?

Only some minerals have the ability to fluoresce under UV light. So what allows some minerals to fluoresce while others cannot?

What's necessary for a mineral to fluoresce? An activator! There is typically a trace amount of "impurities" present within a mineral, which serves as an activator to allow for UV fluorescence. 

Elements like Lead, Manganese, Uranium, Chromium, and rare earth elements (REE) like Yttrium or Europium can serve as activators, causing minerals to fluoresce. These elements are present in such small concentrations they are not typically identified in a minerals main chemistry. 

For example, Fluorite's chemistry is calcium difluoride (CaF2). But tiny amounts of REE like Yttrium or Europium may be present in a Fluorite specimen, a small impurity but enough to serve as an activator to cause the Fluorite to fluoresce a brilliant blue color under UV light.

Fluorescence may also be caused by structural "defects" within the crystal, though this is less common.

A Ruby (Corundum) crystal under regular light (left) and UV fluorescence (right)

A Ruby (Corundum) crystal under regular light (left) and UV fluorescence (right)


Do Fossils Fluoresce?


Yes! Many fossils are the remains of organisms replaced by mineralization. That means minerals, just like the ones you have in your crystal cabinet can be found in certain fossils. For example, Calcite and Aragonite found in Ammonite shells will often fluoresce under UV light!


An Ammonite fossil displayed under regular light (left) and UV fluorescence (right)

An Ammonite fossil displayed under regular light (left) and UV fluorescence (right)


What is Phosphorescence?

Fluorescent materials cease to glow nearly immediately when the radiation source stops. That means when you shine a UV light on a fluorescent mineral, it was glow, then stop glowing when the light is turned off.

Phosphorescent materials on the other hand, will continue to emit light for some time after the source of UV light is turned off. The electrons that are charged with energy take a longer time to dissipate back to their grounded state. That means you can shine your UV light on a specimen, it will fluoresce, and as you turn the UV light off it will phosphoresce or glow for a second or two longer.



A Selenite (Gypsum) crystal cluster under regular light (top left) and displaying UV fluorescence (top center), followed by a time lapse progression of Phosphorescence

A Selenite (Gypsum) crystal cluster under regular light (top left) and displaying UV fluorescence (top center), followed by a time lapse progression of Phosphorescence


How to Make Minerals Fluoresce?

UV Lights, or UV flashlights come in a variety of different wavelengths. When we shine a UV light on our mineral specimens, we're essentially putting energy on these specimens in the form of different frequency wavelengths. 

Long wave (UVA) - least amount of UV energy, 315 to 400 nanometers (nm)

Medium or Mid wave (UVB) - middle amount of UV energy, 280 to 315 nm

Short wave (UVC) - higher amount of UV energy on the spectrum, 100 to 280 nm

Some minerals will only display UV fluorescence under certain wavelengths (long or short), while others will actually show different colors under both short wave and long wave UV light depending on the wavelength. 

Conclusion

Fluorescent minerals and fossils add an extra layer of awesome to your collection. They are a fun and illuminating way to observe your crystals and fossils in a new light (literally)! We hope you've enjoyed learning about fluorescence, and if you're looking to add a new piece to your collection, you can Shop Here!


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